The defending men's champion is first up on Centre Court at 1pm against Britain’s James Ward.
The Spanish women's second seed, Garbiñe Muguruza, who was runner-up to Serena Williams last year, is next on against the Italian Camila Giorgi.
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Then seven-time winner Roger Federer will play Argentinian Guido Pella.
On No1 Court, five-times champion Venus Williams will face Donna Vekic and Kei Nishikori will take on Sam Groth.
