It happened at about five past five when he was seen going into the river from the new Suir bridge on the city bypass.
A search operation immediately began, involving all the emergency services and local volunteer river rescue groups, as well as the Waterford based Coastguard helicopter.
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Gardai in Waterford are appealing to anyone who was travelling on the bypass or bridge at around 5 o'clock yesterday evening and who saw anything to contact them.